04.06.01 Chemical Sciences
DEVELOPMENT OF HIGHLY EFFECTIVE SYNTHETIC METHODS FOR OBTAINING DIFFERENT CLASSES OF PERSPECTIVE COMPOUNDS
Scientific direction:
Domino and other transformations in the (het) arena series to obtain promising fluorophores, (bio) chemosensors and ligands
Studied aspects:
· Fundamentals of organic chemistry
· Synthetic organic chemistry
· Photochemistry / photobiology / photophysics
· Analytical chemistry
· Chemistry of materials, supramolecular chemistry, molecular recognitio
· Physical and colloid chemistry
· Medical and pharmaceutical chemistry
The most striking scientific results:
· Laboratory prototypes of devices operating on the "electronic nose" principle for the detection of explosives
· Synthesized various representatives (element) of organic fluorophores, including for visualization of biological processes, as well as chemosensors for various analytes
· Synthetic methods for single-stage / one-reactor production of various classes of compounds with the participation of high-reaction intermediates have been developed.
Career opportunities:
Employment opportunity, career growth, internships in foreign universities, participation in scientific conferences in Russia and abroad, publications in high-rating journals
Additional requirements of the supervisor:
· Purposefulness and hard work
· Ability for independent research
· Initiative and non-standard thinking
Main publications:
· G.V. Zyryanov et al. Studies on the interactions of 5-R-3-(2-pyridyl)-1,2,4-triazines with arynes: Inverse demand aza-Diels-Alder reaction versus aryne-mediated domino process, Org. Biomol. Chem., 2018, DOI: 10.1039/C8OB00847G
· G.V. Zyryanov et al. Copper nanoparticles as inexpensive and efficient catalyst: A valuable contribution in organic synthesis, Coordination Chemistry Reviews, 2017, 353, 1–57.
· G.V. Zyryanov et al. Solvent-free synthesis of (poly)thiacalix[n]arenes: the evaluation of possible mechanism based on semi-preparative HPLC separation and mass-spectrometric investigation of the reaction products, Arkivoc, 2017, part v, 159-171.
· G.V. Zyryanov et al. Brønsted acidic ionic liquid-catalyzed tandem reaction: an efficient approach towards regioselective synthesis of pyrano[3,2-c]coumarins under solvent-free conditions bearing lower E-factors, Green Chem., 2017, 19, 3282-329.
· G.V. Zyryanov et al. Solvent-free synthesis of 5-(aryl/alkyl)amino-1,2,4-triazines and α-arylamino-2,2′-bipyridines with greener prospects. RSC Advances, 2017, 7, 9610-9619
· G.V. Zyryanov et al. Solvent-free synthesis of pillar[6]arenes. Green Chemistry, 2016, 18, 423-426.
· Zyryanov G.V. et al. First supramolecular sensors for phosphonate anions. Chemical Science, 2013, 4, 3617-3623.
Zyryanov, G.V. et al. Iptycene-based fluorescent sensors for nitroaromatics and TNT. Chemistry - A European Journal, 2012, 18(40), 12712-12718
Contacts
Created / Updated: 24 March 2019 / 9 February 2022
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